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34. Merely observing that all the theorems in integration given in the Preliminary and ivth chapters of Maxwell’s treatise on Electricity and Magnetism, Part i., are easy particular cases of equations (8) and (9) Section 4 above, we pass on to the one application of Quaternions that we propose to make in Electrostatics.
This is to find the most general mechanical results arising from Maxwell’s theory of Electrostatics, and to see if they can be explained by stress in the dielectric. This problem as far as I am aware has not hitherto in all its generality been attacked though the most important practical cases have been, as we shall see, considered by Maxwell, Helmholtz, Korteweg, Lorberg and Kirchhoff.
It is necessary first of all to indicate as clearly as possible what I take to be Maxwell’s theory of Electricity.
He assumes25 all space to be uniformly filled with a certain substance called Electricity. Whatever electrical actions take place depend on the continued or past motion of this substance as an incompressible fluid. If electricity is brought from a distance by any means and placed in a given space there must be a displacement of the original electricity outwards from that space and the quantity of foreign electricity is conveniently measured by the surface integral of that displacement.
Dielectrics are substances in which this displacement tends to undo itself, so to speak, i.e. the original electricity tends to go back to its primitive position. In conductors, on the other hand, there is no property distinguishing any imported electricity from the original electricity.
The rate of variation of displacement, whether in dielectrics or conductors, of course constitutes an electric current as it is conveniently called.
We have next to consider a vector at each point of space called the electro-motive force, which depends in some way at present undefined on the distribution of the displacement in the dielectrics, the distribution of currents whether in dielectrics or conductors, and on extra-electrical or semi-electrical action, e.g. chemical or mechanical.
If at any point the electro-motive force be multiplied by a scalar the medium at the point remaining (except electrically) unchanged, the current in the case of conductors and the displacement in the case of dielectrics is altered in the same ratio. In other words the current or the displacement, as the case may be, is a linear vector function of the electro-motive force, and the coordinates of the linear vector function26 at any point depend solely on the state of the medium (whether fluid, solid, &c., or again strained or not) at that point.
To complete the theory we have to explain how the part of the electro-motive force which is a function of the distribution of displacement and current depends on this distribution. This explanation is obtained by making the assumption that the electro-motive force bears to electricity defined as above exactly the same energy relation as ordinary force does to matter, i.e.—
In the ivth part of Maxwell’s treatise he gives complete investigations of the mechanical results flowing from this theory so far as it refers to currents, but he has not given the general results in the case of Electrostatics. Nor has he shewn satisfactorily, it seems to me, that the ordinary laws of Electrostatics flow from his theory. It is these investigations we now propose to make.
35. Our notation will be as far as possible the same as Maxwell’s. Thus for the displacement at any point we use , and for the e.m.f. . From the connection explained in last section between and we have
where at any point is some linear vector function depending on the state of the medium at the point. If the medium change in any manner not electrical, e.g. by means of ordinary strain will in general also suffer change.
Let be the potential energy per unit volume due to the electrical configuration. Thus if a small increment be given to at all points, the increment in , the potential energy of the electrical configuration in any space, = work done on the electricity in producing the change,
by the relation stated in Section IV existing between and . Thus limiting the space to the element
Now suppose so that by equation (1) where , are corresponding e.m.f. and displacement respectively. Thus
Integrating from to , and finally changing , into , we get
From this we get
so that by equation (2) or by equation (1)
Hence (because and are quite arbitrary) is self-conjugate and therefore involves only six instead of nine coordinates27.
In electrostatics the line integral of round any closed curve must be zero, for otherwise making a small conductor coincide with the curve we shall be able to maintain a current by Section IV, and so (by the same section) constantly do work on it (i.e. as a matter of fact create heat) without altering the statical configuration. Hence must have a potential, say . Thus
Since in an electrostatic field there is no current in a conductor, throughout any such conductor and therefore
36. The charge in any portion of space is defined as the amount of foreign electricity within that space. Thus the charge in any space is the surface integral of the displacement outwards. Thus if there be a charge on the element of a surface in the dielectric this charge where , denote the two faces of the element (so that ) and in accordance with Section 1 above points away from the region in which the displacement is . Thus being the surface density
where the notation is used for . Similarly if there be finite volume density of foreign electricity, i.e. finite volume density of charge in any space, the charge , so that if be the volume density
[The reason for having before and here is that in the former case we were considering a charge outside the region where is considered—between the regions and in fact—whereas in the latter case we are considering the charge inside the region where is considered. The same explanation applies to the sign of for the surface of a conductor given below.]
In conductors, as we saw in Section IV, the displacement has virtually no meaning (except when it is changing and so the phenomenon of a current takes place) for the foreign electricity and the original electricity are not to be distinguished. Not so however with the surface of the dielectric in contact with the conductor. We may therefore regard the electricity within the body of the conductor as the original electricity so that the charge is entirely at the surface. Thus the surface density will be where points away from the conductor and is the displacement in the dielectric. This may be regarded as a particular case of equation (5) being in accordance with what we have just said considered as zero in the conductor.
37. All the volume integrals with which we now have to deal may be considered either to refer to the whole of space or only to the dielectrics, as the conductors (except at their surfaces) in all cases contribute nothing. The boundary of space will be considered as a surface at infinity and all surfaces where either or is discontinuous.
Putting we have already found one expression for , viz.
We now give another. By equation (4)
by equation (9) Section 4 above. Thus by equations (5) and (6) Section IV,
where is put, as it frequently will be, for an element of surface, i.e. . The value of which we shall use28 is obtained by combining these two, viz.
So far we have merely been shewing that all the above results of Maxwell’s flow from what in Section IV has been described as his theory. We now proceed to the actual problem in hand which is proved from these results however they may be obtained. I may remark that some such investigation as the above seems to me necessary to make the logic of Maxwell’s treatise complete.
38. Suppose now that is the potential energy of some dynamical system extending throughout space. Let us give to every point of space a small displacement vanishing at infinity and find the consequent increment in . If this can be put in the form
we shall have the following expression for the force per unit volume due to the system
and the following expression for the force per unit surface at any surface of discontinuity in
the notation being the same as in equation (5) Section IV.
Moreover if be self-conjugate the forces both throughout the volume and at surfaces of discontinuity are producible by the stress as can be seen by Section 7 above. [Compare all these statements with Section 8 above.]
For proof, we have by equation (9) Section 4
where of course the element is taken twice, i.e. once for each face. But
where the element is taken only once. Equating the coefficients of the arbitrary vector for each point of space we get the required equations (10) and (11).
39. We must then put where is given by equation (8) in the form given in equation (9).
We must first define when applied to a function of the position of a point. Suppose by means of the small displacement any point moves to . Then being the value at , before the displacement , of a function of the position of a point, is defined as the value of the function at after the displacement. Thus even in the neighbourhood of a surface of discontinuity is a small quantity of the same order as .
Now the charge within any space, that is the quantity of foreign electricity within that space will not be altered by the strain.
To find we have
or, since ,
The part of depending on the first two terms of equation (8) is by equation (12)
Noticing that and that we see that the last term in equation (8) contributes
Combining the last result with the first term of this we get
Thus we have
40. Now the increment in is caused by two things viz. the mere rotation of the body and the change of shape of the body. Let us call these parts and respectively.
First consider . Suppose the rotation is so that any vector which was becomes thereby . Thus the result of operating on by is the same as first operating on by and then rotating. In symbols
whence giving its value ,
Substituting in equation (14)
or
It only remains to consider . is a function of the pure strain of the medium and is the increment in due to the increment in pure strain owing to . Calling this increment of pure strain so that by equation (3) Section 7 above
we have
Now by equations (1) and (3) Section IV,
so that is a function of the independent variables , (because is a function of ). Therefore
This equation might have been deduced at once thus
but equation (17) is itself of importance so the above proof is preferable.
Thus finally from equation (15) we get
We therefore have for in equations (10) and (11) Section IV,
This is a self-conjugate function so that as we saw in Section IV it is a stress which serves to explain forces both throughout the volume of the dielectric and over any surfaces of discontinuity in or 29.
41. Let us first consider that part of the force equations (10) Section IV and (21) Section IV which does not depend on the variation of with the shape of the body.
Suppose our dielectric is homogeneous and electrically isotropic so that is a simple constant scalar. In this case
by equations (1) and (4) Section IV. Therefore by equations (5) and (6) Section IV,
From these we at once get by the theory of potential that
From this we know by the theory of potential that at the surface where the charge resides is discontinuous only with regard to its normal component and at all other points is continuous. Thus
and by equation (24) so that
Now the force per unit volume is
and the force per unit surface is by equation (11) Section IV,
whence by equation (26)
Thus we see that Maxwell’s theory as given in Section IV above reduces to the ordinary theory when is a single scalar. In fact two particles containing charges apparently repel one another with a force where is the distance between them, for by equations (25), (27) and (28) the force in any charged body is that due to a field of potential given by
42. If the medium when strained remain electrically isotropic as well as must be a simple scalar. Thus with Thomson and Tait’s notation for strain, which makes the coordinates of , , , , , , we have
Therefore is a function of only, i.e. of the density () of the medium. Thus because
we get suppose. Hence
Thus the force [equations (21) Section IV and (10) Section IV] resulting from the change of with pure strain is in the case we are now considering
and is30 therefore, according as is positive or negative, in the direction of or that opposite to that of the most rapid increase of the square of the electro-motive force. Thus even in the case of a fluid dielectric which has no internal charge but which forms part of a non-uniform field of (electro-motive) force the surfaces of equal pressure and therefore the free surface will if originally plane no longer remain so.
Nature of the Stress
43. We have seen that the stress which serves to explain the electrostatic forces is that given by equation (21) Section IV, viz.
Let us first consider the part which does not depend on the variation of . Putting first and then we get
Therefore putting first any multiple of and then any multiple of we get
Lastly, since
we see that if we put any multiple of
Thus we see that the stress now considered is a tension along one of the bisectors of and (the bisector of the positive directions or the negative directions of both) , an equal pressure along the other bisector and a pressure perpendicular to both these directions. When is parallel to this at once reduces to Maxwell’s case, viz. a tension in the direction of and a pressure in all directions at right angles each .
44. We have now to consider the other part of the stress, viz.
If we assume that is a function of the density () of the medium only we shall have
say, and
as in Section 14. Here however is not in general a mere scalar but a self-conjugate linear vector function. We have then in this case
which is a hydrostatic pressure or an equal tension in all directions according as is positive or negative. In this case the 36 coordinates of reduce to the 6 of for each point of space.
A more general assumption is that (Section IV) depends only on the elongations in the directions of the principal axes of . Taking , , as unit vectors in these directions we again have
and similarly for and , so that the principal axes of the stress now considered are the principal axes of .
4531. The most natural simple assumption for solid dielectrics seems to me to be that the medium is electrically isotropic before strain, and also isotropic with regard to the strain in the sense that if the strain be, so to speak, merely rotated, will suffer exactly the same rotation. We may treat this problem exactly as we did (Section 11) that of stress in terms of strain for an isotropic solid. Thus splitting up into its principal elongations, i.e. putting
we shall get, as in Section 11,
But by equation (16) Section IV, so that from equation (31)
whence we see by Section 2 above that
which consists of a pressure in the directions of the lines of force and another pressure in all directions at right angles .
Magnetism
beginalign*2ex] Magnetic potential, force, induction
46. We now go on to the ordinary theory of magnetism; and here we shall merely follow Maxwell in his General Theory, so as to give an opportunity of comparing Quaternion proofs with Cartesian, as we have already done in Elasticity.
We shall not consider in detail the effect of one small magnet upon another, as this has already been done by Tait. In connection with this I am content to remark that I think the treatment of this problem can be made somewhat simpler than Tait’s by means of potential.
Suppose we have a pole at and a pole at where is small. Calling the vector from to , let us call the vector , so that is the vector magnetic moment of the magnet. The potential of at any point is , where as usual . Similarly the potential of is , where . Therefore the potential of the magnet
where of course is the variable point implied by . Thus the potential of a small magnet at any point .
Hence the potential of any magnet whose magnetic moment per unit volume at any point is is
according to the convention of Section 5 above. By equation (9) Section 4 this may be put
which shews that we may consider it due to a volume density and a surface density 32 of magnetic matter, the surface density occurring wherever there is discontinuity in .
By again considering the poles and of the small magnet we see that its potential energy when placed in a field of magnetic potential is , whence just as we obtained equation (33) we now see that the potential energy () of any magnet in such a field is
by equation (9) Section 4 above, so that the potential energy is just the same as it would be for the imaginary distribution of magnetic matter.
47. The force () on a unit magnetic pole at any point external to the magnet is given by
where
Thus we see that for all external points , so that is called the vector magnetic potential. [It is to be observed that since a vector, .] is called the magnetic induction and for it we use the single symbol so that
and also by the equation for just given
This is not the way in which Maxwell defines the magnetic force and induction, but he shews quite simply (Elect. and Mag. §§ 398–9) that his definition and the present one are identical. This can be shewn as easily without analysis at all.
48. Where is discontinuous both and are also discontinuous. From the surface density view we gave in equation (34) we see that, just as we have the expression, given in Section 14 for , so now
so that the discontinuity in is entirely normal to the surface of discontinuity. Further from this equation we have
so that the discontinuity in is entirely tangential.
From this equation we see that for any closed surface whatever whether it include surfaces of discontinuity in or not
For adding these surfaces to the boundary of the inclosed space, in accordance with Section 4 above, we see by equation (42) that they contribute zero to the surface integral; but the total surface integral is by equation (9) Section 4 by equation (39).
Magnetic Solenoids and Shells
49. A magnet is said to be solenoidal if the imaginary magnetic matter of equation (34) is entirely on the surface. Thus for a solenoidal distribution
In this case the potential is by equation (34)
50. A simple magnetic shell is defined as a sheet magnetised everywhere normally to itself and such that, at any point, the magnetic moment per unit surface is a constant called the strength of the shell.
Calling the strength we have for the potential energy at any point by equation (33)
Now is the solid angle subtended by the element at the point considered, so that
Thus if be a point on the positive side of the shell and a point infinitely near but on the negative side
or what comes to the same thing
This integral may be taken along any path, e.g. along a path which nowhere cuts the shell. The same integral is true if be the magnetic force due to a whole field of which the shell is only one of several causes, for the part contributed by the rest of the field is zero on account of the infinite proximity of and . For future use in electro-magnetism observe that this statement cannot be made if for in the integral be substituted .
51. The condition that any magnet can be divided up into such shells is at once seen to be that can be put in the form
where is some scalar.
In this case the potential is by equation (33)
Remarking that the solid angle again occurs here it is needless to interpret the equation further. By equation (37) we have for the vector potential
52. The potential energy of a magnetic shell of strength placed in a field of potential is of importance. We see by equation (35) that it is
If then the magnets which cause do not cut the shell anywhere, so that , we shall have
Suppose now that is caused by another shell of strength . Then by equation (49)
by equation (8) Section 4. Thus finally the potential energy of these two shells is given by
53. The general theory of induced magnetism when once the proposition (given in equation (42) Section 14) that is zero is established, is much the same whether treated by Quaternion or Cartesian notation. We shall therefore not enter into this part of the subject.
Electro-magnetism
beginalign*2ex] General theory
54. We now propose to prove the geometrical theorems connected with Maxwell’s general theory of Electro-magnetism by means of Quaternions.
We assume the dynamical results of Chaps. V., VI. and VII., and the first six paragraphs of Chap. VIII. of the fourth part of his treatise.
These assumptions amount to the following. Connected with any closed curve in an electro-magnetic field there is a function
where is some vector function at every point of the field. The function has the following properties. If any circuit be made to coincide with the curve the generalised force acting upon the electricity in the circuit is
Again, if there be a current of electricity flowing round this circuit, the generalised force , corresponding to any coordinate of the position of the circuit due to the field acting upon the conductor, is
55. The first thing to be noticed is that can be transformed into a surface integral by equation (8) Section 4 above.
Next we see by the fundamental connection (Section IV above) between the e.m.f. and electricity, that must equal the line integral of round the circuit, or
We are now in a position to find in terms of and , i.e. of .
56. The rate of variation of is due to two causes, viz. the variation of the field () and the motion of the circuit (). In the time then there will be an increment in and an increment in to be considered. Thus
[This amounts to assuming that , which of course is true by equation (8) Section 4.] Now when the circuit changes slightly we may suppose the surface over which the new integral extends to coincide with the original surface and a small strip at the boundary traced out by the motion () of the boundary. Thus is zero everywhere except at the boundary and there it
where is a scalar and is put as the most general vector whose line integral round any closed curve is zero.
57. We now come to the mechanical forces exerted on an element through which a current per unit volume flows.
We see by equation (55) that the work done by the mechanical forces on any circuit through which a current of magnitude flows in any small displacement of the circuit equals the increment in caused by the displacement. Give then to each element of the circuit an arbitrary small displacement and let be the mechanical force exerted by the field upon the element. Thus as in last section
Thus the force on the element is . But we may suppose this element to be an element of volume through which the current flows. Thus if for we write , and for , , where is the force per unit volume exerted by the field, we get
58. So far we have been able to go by considering the electric field as a mechanical system, but to go further (as Maxwell points out) and find how or depends on the distribution of current and displacement in the field we must appeal to experiment. It has been shewn by experiment that a small circuit produces exactly the same mechanical effects on magnets as would a small magnet, at the same point as the circuit, placed with its positive pole pointing in the direction of the positive normal to the plane of the circuit when the positive direction round the circuit is taken as that of the current33. Moreover the magnetic moment of the magnet which must be placed there is proportional to the strength of the current the area of the circuit. Further, the effect of this circuit upon other such small circuits is the same as the mutual effects of corresponding magnets. We have now only to consider a finite circuit as split up in the usual way into a number of elementary circuits to see that a finite circuit will act upon magnets or upon other circuits exactly like a magnetic shell of strength proportional to the strength of the current and boundary coinciding with that of the circuit. The unit current in the electro-magnetic system is so taken as to make this proportionality an equality.
The one difference between the circuit and the magnetic shell is that there is no discontinuity in the magnetic potential in going round the circuit, so that by Section 14 above the line integral of round the circuit will be the strength of the current. In symbols
for any curve, so that by equation (8) Section 4
which of course is a direct result of our original assumption that electricity moves like an incompressible fluid. Maxwell tacitly assumes this by making the assumption that only one coordinate is required to express the motion of electricity in a circuit.
59. We are now in a position to identify the we are now using with the magnetic induction for which we have already used the same symbol.
We see by equation (50) Section 14 that the mechanical force on the shell corresponding to any coordinate is
where is the magnetic induction; and by equations (53) and (55) that the force on the corresponding electric circuit is
therefore wherever there is no magnetism. And where there is magnetism is not for , as we have seen. Thus at all points. In other words the two vectors are identical and we are justified in using the same symbol for the two.
This practically ends the general theory of electro-magnetism. We content ourselves with one more application of Quaternions in this subject. We give it because it exhibits in a striking manner the advantages of Quaternion methods.
Electro-magnetic phenomena explained by Stress
60. In Section 14 equation (35) we have seen that the potential energy of a magnetic element in a magnetic field is when has a potential. Maxwell assumes that the same expression is true whether have a potential or not. Assuming this point34 with him we can find the force and couple acting on the medium and a stress which will produce that force and couple. The force and couple due to the magnetism of an element is obtained by giving the element an arbitrary translation and rotation and assuming that the work done by this force and couple = the decrement in the potential energy of the element. Thus the force per unit volume is for the decrement in the potential energy due to a small translation is . Similarly the couple is given by
for the decrement in the potential energy due to a small rotation is . The total force per unit volume is the sum of that just given and that given by equation (61), so that
Therefore by equation (62)
Now so that , and again
From these two results equations (65) and (67) we see by Section 7 above that the stress will produce all the mechanical effects of the field.
This stress, as can be seen by giving the required values in equation (66), is one of pressure in all directions at right angles to and of tension in the direction of . When there is no magnetism so that this pressure and tension become equal and their directions at right angles to and along respectively. In fact we then have
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